纺织学报 ›› 2021, Vol. 42 ›› Issue (12): 188-195.doi: 10. 13475/j.fzxb.20201201008

• 综合述评 • 上一篇    下一篇

金属-有机骨架光催化降解染料的研究进展

李庆1(), 陈灵辉1, 李丹1, 吴志强1, 朱炜1, 樊增禄2   

  1. 1.西安工程大学 西安市纺织化工助剂重点实验室, 陕西 西安 710048
    2.功能性纺织材料及制品教育部重点实验室(西安工程大学), 陕西 西安 710048
  • 收稿日期:2020-12-04 修回日期:2021-09-10 出版日期:2021-12-15 发布日期:2021-12-29
  • 作者简介:李庆(1983—),男,副教授,博士。主要研究方向为金属-有机骨架的构筑及水环境修复。E-mail: liqingxpu1@163.com。
  • 基金资助:
    国家自然科学基金面上基金项目(22078253);陕西省重点研发项目(2020GY-276);陕西省教育厅服务地方专项(19JC016);西安市科技计划项目(2019217114GXRC007CG008-GXYD7.1);西安市碑林区科技计划项目(GX2003);国家级大学生创新训练计划项目(S202010709027)

Research progress in photocatalytic degradation of dyes using metal-organic frameworks

LI Qing1(), CHEN Linghui1, LI Dan1, WU Zhiqiang1, ZHU Wei1, FAN Zenglu2   

  1. 1. Xi'an Key Laboratory of Textile Chemical Engineering Auxiliaries, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China
    2. Key Laboratory of Functional Textile Material and Product(Xi'an Polytechnic University), Ministry of Education, Xi'an, Shaanxi 710048, China
  • Received:2020-12-04 Revised:2021-09-10 Published:2021-12-15 Online:2021-12-29

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摘要：

为促进金属-有机骨架(MOFs)在印染废水处理中的应用,对MOFs光催化降解染料的研究进展进行综述。阐述了MOFs的制备方法和空间结构的高可设计性,分析了提升MOFs可见光催化降解能力的策略:采用发色团修饰的有机配体来构筑高可见光响应性的MOFs;选取高可见光敏感的客体分子,通过物理吸附进入MOFs内部空腔或附着于其表面进行后修饰,构建出具有高可见光催化降解效能的MOFs复合材料。论述了提升MOFs循环使用能力即实用性的思路和方法,并分析了MOFs的光催化降解效果和染料降解产物。最后指出:开展基于高水稳定性MOFs的光敏后修饰研究,探索该材料与其他传统材料和技术结合,是推进MOFs在印染废水处理领域应用的努力方向。

关键词: 金属-有机骨架, 光催化降解, 染料, 可见光响应性, 稳定性, 染色废水, 废水处理

Abstract:

To promote the applications of metal-organic frameworks (MOFs) in dyeing wastewater treatment, research progress in using MOFs for photocatalytic degradation of dyes were reviewed. Preparation methods and high designability of their space structures were introduced, and strategies for enhancing their visible photocatalytic degradation capabilities were analyzed, including the use of organic ligands modified by chromophore to construct highly visible-light responsive MOFs. The review revealed that construction of MOFs composites with high visible-light catalytic degradation efficiency was achieved by selecting highly visible-light sensitive guest molecules and making them into the inner spaces or on the surface of MOFs for post-modification. Ideas and methods to improve the recycling ability of MOFs were discussed. The degradation performance and products of dye molecules were described and analyzed. Researches on photosensitive post-modification based on highly water stable MOFs, and exploration of the combination of this material with other traditional materials and technologies, have been suggested to be the direction for promoting the applications of MOFs in dyeing wastewater treatment.

Key words: metal-organic framework, photocatalytic degradation, dyes, visible-light responsiveness, stability, dyeing wastewater, wastewater treatment

中图分类号: 

  • TS190.2

图1

MOFs的制备方法"

图2

MOF-5与MOF-199的解构过程及拓扑结构"

图3

MOFs之间的带隙和光源(紫外光或可见光)比较以及染料敏化MOFs(宽带隙)系统中的电子转移途径"

图4

对苯二甲酸配体及其功能基团修饰"

图5

三原色光敏剂敏化的In-MOF对RB21高效而差异性的光催化降解能力"

图6

甲基改性配体构筑高水稳定Zr-MOF"

图7

高水稳定性的Zr-MOF复合材料可见光催化降解RB21"

图8

LC-MS检测的MB分子降解路径"

[1] KHASEVANI S G, GHOLAMI M R. Synjournal of BiOI/ZnFe2O4-metal-organic framework and g-C3N4 based nanocomposites for applications in photocatalysis[J]. Industrial & Engineering Chemistry Research, 2019, 58(23):9806-9818.
doi: 10.1021/acs.iecr.8b05871
[2] ROJAS S, HORCAJADA P. Metal-organic frameworks for the removal of emerging organic contaminants in water[J]. Chemical Reviews, 2020, 120(16):8378-8415.
doi: 10.1021/acs.chemrev.9b00797
[3] 李庆, 张莹, 樊增禄, 等. Cu-有机骨架对染料废水的吸附和可见光降解[J]. 纺织学报, 2018, 39(2):112-118.
LI Qing, ZHANG Ying, FAN Zenglu, et al. Adsorption and visible-light photodegradation of dye wastewater over Cu-organic framework[J]. Journal of Textile Research, 2018, 39(2):112-118.
[4] LI Q, FAN Z L, XUE D X, et al. Multi-dyes@MOF composite boosts highly efficient photodegradation of ultra-stubborn dye of reactive blue 21 under visible-light irradiation[J]. Journal of Materials Chemistry A, 2018, 6(5):2148-2156.
doi: 10.1039/C7TA10184H
[5] LV S W, LIU J M, WANG Z H, et al. Recent advances on porous organic frameworks for the adsorptive removal of hazardous materials[J]. Journal of Environmental Sciences, 2019, 80(6):169-185.
doi: 10.1016/j.jes.2018.12.010
[6] 李庆, 樊增禄, 张洛红, 等. 锆-有机骨架对水中染料的高选择性可循环吸附[J]. 纺织学报, 2019, 40(2):141-146.
LI Qing, FAN Zenglu, ZHANG Luohong, et al. Preferential and recyclable adsorption of dyes from water by Zr-organic skeleton[J]. Journal of Textile Research, 2019, 40(2):141-146.
[7] LI Q, CAI X B, CHEN L H, et al, Hydrolytically stable and trifunctional zirconium-based organic frameworks toward Cr2O2-7 detection, capture, and photoreduction[J]. Inorganic Chemistry, 2021, 60(5):8143-8153.
doi: 10.1021/acs.inorgchem.1c00794
[8] 朱炜, 李庆, 张萍, 等. MOF-177吸附CO2、CH4的模拟研究[J]. 纺织高校基础科学学报, 2018, 31(1):90-96.
ZHU Wei, LI Qing, ZHANG Ping, et al. Simulation study of the adsorption of CO2, CH4 by MOF-177[J]. Basic Sciences Journal of Textile Universities, 2018, 31(1):90-96.
[9] DHAKSHINAMOORTHY A, LI Z H, GARCIA H. Catalysis and photocatalysis by metal organic frame-works[J]. Chemical Society Reviews, 2018, 47(22):8134-8172.
doi: 10.1039/C8CS00256H
[10] YANG Q L, XU Q, JIANG H L. Metal-organic frameworks meet metal nanoparticles: synergistic effect for enhanced catalysis[J]. Chemical Society Reviews, 2017, 46(15):4774-4808.
doi: 10.1039/C6CS00724D
[11] SUNDINA E, ABRAHAMSSON M. Long-lived charge separation in dye-semiconductor assemblies: a pathway to multi-electron transfer reactions[J]. Chemical Communications, 2018, 54(42):5289-5298.
doi: 10.1039/C8CC01071D
[12] FURUKAWA H, CORDOVA K E, O'KEEFFE M, et al. The chemistry and applications of metal-organic frameworks[J]. Science, 2013, 341(6149):1230444.
doi: 10.1126/science.1230444
[13] ALMEIDA F A, KILNOWSKI J. Hydrothermal synjournal and structural characterization of a novel cadmium-organic framework[J]. Journal of Solid State Chemistry, 2004, 177(10):3423-3432.
doi: 10.1016/j.jssc.2004.05.022
[14] JHUNG S H, LEE J H, FORSTER P M, et al. Microwave synjournal of hybrid inorganic-organic porous materials: phase-selective and rapid crystallization[J]. Chemistry-A European Journal, 2006, 12(30):7899-7905.
doi: 10.1002/(ISSN)1521-3765
[15] LI Q, WU T, LAI J C, et al. Diversity of coordination modes, structures, and properties of chiral metal-organic coordination complexes of the drug voriconazole[J]. European Journal of Inorganic Chemistry, 2015(31):5281-5290.
doi: 10.1002/ejic.v2015.31
[16] FURUKAWA S, REBOUL J, DIRING S, et al. Structuring of metal-organic frameworks at the mesoscopic/macroscopic scale[J]. Chemical Society Reviews, 2014, 43(16):5700-5734.
doi: 10.1039/C4CS00106K
[17] LI M, LI D, O'KEEFFE M, et al. Topological analysis of metal-organic frameworks with polytopic linkers and/or multiple building units and the minimal transitivity principle[J]. Chemical Reviews, 2014, 114(2):1343-1370.
doi: 10.1021/cr400392k
[18] 管斌斌, 李庆, 陈灵辉, 等. 基于锆-有机骨架的印染废水中Cr(VI)的荧光检测[J]. 纺织学报, 2021, 42(2):122-128.
GUAN Binbin, LI Qing, CHEN Linghui, et al. Fluorescence detection of Cr(VI) from printing and dyeing wastewater by zirconium-organic framework[J]. Journal of Textile Research, 2021, 42(2):122-128.
[19] ZHANG T, LIN W B. Metal-organic frameworks for artificial photosynjournal and photocatalysis[J]. Chemical Society Reviews, 2014, 43(16):5982-5993.
doi: 10.1039/C4CS00103F
[20] ALVARO M, CARBONELL E, FERRER B, et al. Semiconductor behavior of a metal-organic frame-work (MOF)[J]. Chemistry-A European Journal, 2007, 13(18):5106-5112.
doi: 10.1002/(ISSN)1521-3765
[21] CANIVET J, FATEEVA A, GUO Y, et al. Water adsorption in MOFs: fundamentals and applications[J]. Chemical Society Reviews, 2014, 43(16):5594-5617.
doi: 10.1039/C4CS00078A
[22] WANG Q, GAO Q Y, AL-ENIZI A M, et al. Recent advances in MOF-based photocatalysis: environmental remediation under visible light[J]. Inorganic Chemistry Frontiers, 2020, 7(2):300-339.
doi: 10.1039/C9QI01120J
[23] CHAMBERS M, WANG X, ELLEZAM L, et al. Maximizing the photocatalytic activity of metal-organic frameworks with aminated-functionalized linkers: substoichiometric effects in MIL-125-NH2[J]. Journal of the American Chemical Society, 2017, 139(24):8222-8228.
doi: 10.1021/jacs.7b02186
[24] MU X X, JIANG J F, CHAO F F, et al. Ligand modification of UiO-66 with an unusual visible light photocatalytic behavior for RhB degradation[J]. Dalton Transactions, 2018, 47(6):1895-1902.
doi: 10.1039/C7DT04477A
[25] 尚启超, 房新佐, 江海龙, 等. 半导体纳米颗粒/金属-有机骨架复合光催化体系中的位置效应[J]. 化学物理学报, 2018, 31(5):613-618.
SHANG Qichao, FANG Xinzuo, JIANG Hailong, et al. Location effect in a photocatalytic hybrid system of metal-organic framework interfaced with semiconductor nanoparticles[J]. Chinese Journal of Chemical Physics, 2018, 31(5):613-618.
[26] DHAKSHINAMOORTHY A, ASIRI A M, GARCÍA H. Metal-organic framework (MOF) compounds: photocatalysts for redox reactions and solar fuel production[J]. Angewandte Chemie International Edition, 2016, 55(18):5414-5445.
doi: 10.1002/anie.v55.18
[27] QIU J, ZHANG X, FENG Y, et al. Modified metal-organic frameworks as photocatalysts[J]. Applied Catalysis B: Environmental, 2018, 231(5):317-342.
doi: 10.1016/j.apcatb.2018.03.039
[28] ZHANG X D, YANG Y, HUANG W Y, et al. g-C3N4/UiO-66 nanohybrids with enhanced photocatalytic activities for the oxidation of dye under visible light irradiation[J]. Materials Research Bulletin, 2018, 99(3):349-358.
doi: 10.1016/j.materresbull.2017.11.028
[29] YUAN Y P, YIN L S, CAO S W, et al. Improving photocatalytic hydrogen production of metal-organic framework UiO-66 octahedrons by dye-sensitization[J]. Applied Catalysis B: Environmental, 2015, 168-169(6):572-576.
[30] 李庆, 管斌斌, 王雅, 等. 光敏剂敏化Cu-有机骨架对活性深蓝K-R的高效光催化降解[J]. 纺织学报, 2020, 41(10):87-93.
LI Qing, GUAN Binbin, WANG Ya, et al. Photosensitizers sensitized Cu-organic framework for highly efficient photocatalytic degradation of reactive dark blue K-R[J]. Journal of Textile Research, 2020, 41(10):87-93.
[31] GIBSON E A. Dye-sensitized photocathodes for H2 evolution[J]. Chemical Society Reviews, 2017, 46(20):6194-6209.
doi: 10.1039/C7CS00322F
[32] WANG C, LIU X, DEMIR N, et al. Applications of water stable metal-organic frameworks[J]. Chemical Society Reviews, 2016, 45(18):5107-5134.
doi: 10.1039/C6CS00362A
[33] BURTCH N, JASUJA H, WALTON K. Water stability and adsorption in metal-organic frameworks[J]. Chemical Reviews, 2014, 114(20):10575-10612.
doi: 10.1021/cr5002589
[34] WANG B, LV X L, FENG D W, et al. Highly Stable Zr(IV)-based metal-organic frameworks for the detection and removal of antibiotics and organic explosives in water[J]. Journal of the American Chemical Society, 2016, 138(19):6204-6216.
doi: 10.1021/jacs.6b01663
[35] LI Q, FAN Z L, ZHANG L H, et al. Boosting and tuning the visible photocatalytic degradation performances towards reactive blue 21 via dyes@MOF composites[J]. Journal of Solid State Chemistry, 2019, 269(1):465-475.
doi: 10.1016/j.jssc.2018.10.025
[36] PEARSON R G. Hard and soft acids and bases[J]. Journal of the American Chemical Society, 1963, 85(22):3533-3539.
doi: 10.1021/ja00905a001
[37] HOWARTH A J, LIU Y, LI P, et al. Chemical, thermal and mechanical stabilities of metal-organic frameworks[J]. Nature Reviews Materials, 2016, 1(3):15018.
doi: 10.1038/natrevmats.2015.18
[38] BAI Y, DOU Y, XIE L, et al. Zr-based metal-organic frameworks: design, synjournal, structure, and applications[J]. Chemical Society Reviews, 2016, 45(8):2327-2367.
doi: 10.1039/C5CS00837A
[39] 李庆. 水稳定型In/Zr-有机骨架材料的设计、合成与光催化降解有机染料[D]. 西安: 陕西师范大学, 2017: 105-143.
LI Qing. Design, synthesis and photocatalytic degradation of organic dues by water stable In/Zr-organic frameworks materials[D]. Xi'an: Shaanxi Normal University, 2017: 105-143.
[40] FAN G D, LUO J, GUO L, et al. Doping Ag/AgCl in zeolitic imidazolate framework-8 (ZIF-8) to enhance the performance of photodegradation of methylene blue[J]. Chemosphere, 2018, 209(19):44-52.
doi: 10.1016/j.chemosphere.2018.06.036
[41] HU L X, DENG G H, LU W C, et al. Peroxymonosulfate activation by Mn3O4/metal-organic framework for degradation of refractory aqueous organic pollutant rhodamine B[J]. Chinese Journal of Catalysis, 2017, 38(8):1360-1372.
doi: 10.1016/S1872-2067(17)62875-4
[42] ARAYAABC T, CHEN C C, JIA M K, et al. Selective degradation of organic dyes by a resin modified Fe-based metal-organic framework under visible light irradia-tion[J]. Optical Materials, 2017, 64(2):512-523.
doi: 10.1016/j.optmat.2016.11.047
[43] LV H L, ZHAO H Y, CAO T C, et al. Efficient degradation of high concentration azo-dye wastewater by heterogeneous Fenton process with iron-based metal-organic framework[J]. Journal of Molecular Catalysis A: Chemical, 2015, 400(5):81-89.
doi: 10.1016/j.molcata.2015.02.007
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